So the problem Drew mentioned, of mapping between different sets of sync folders on different machines, is transformed into mapping an identical folder hierarchy (i.e. the dropbox folder and contents) to arbitrary sync files/folders, done by the user, for that specific machine.
You get the simple, instant user model (dropbox folder), which you can customize to any arbitrary user model, as much or as little as you want, when you want it. And simple syncing.
Then when you setup a new machine - install dropbox and let it sync, then just symlink them back up... everything is back to normal.
Really a nice setup so you can continue to change your config files and not worry about saving the changes to some backup gist or something