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From a young age I've combed the shelves at public libraries and found handbooks on battery technology.

Often 1/3 of the book is devoted to ordinary batteries and the other 2/3 are devoted to "reserve batteries" which are able to deliver a high power density for a short time to power a missile or something like that. There was a huge amount of research on those and I think it's easier to make a battery work if it doesn't have to last very long.

NiMH batteries seemed to come out of nowhere. I remember Sony licensing the technology for "InfoLithium" batteries that eventually took over the world.

The market for batteries is bigger than it ever was. Grid scale batteries relax many constraints: molten salt batteries might be practical there. The South Africans thought this kind of battery might be relevant for cars in the late 1970's and 1980's

https://www.afrik21.africa/en/south-africa-the-zebra-salt-ba...

and it might be again with electric cars legitmized and if oil is out of reach.



>NiMH batteries seemed to come out of nowhere.

My initial thought when I saw your post was "weren't these just a relatively contemporaneous improvement on NiCad batteries?"

Checked Wikipedia and nope:

NiCad - Invented in 1899 and commercialized in 1910.

NiMH - Invented in 1967 and commercialized in 1989.

I had no idea there was such a long gap between the two.


I wonder if there was some kind of economic inflection point — it felt like that in my memory, too, where it felt like NiCad was advertised more as new thing in the 80s before getting replaced with NiMH. I wonder how much that perception was steered by what was common in the car battery space since that was probably the most known rechargeable battery for a long time.


In the RC car world, NiCad to NiMH was a big deal.


I think sodium ion will dominate the next 10 years of grid storage unless a sulfur battery like this can commercialize fast enough.

The sulfur chemistries might leave all the solid state stuff in the dust.




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