This has already been an area of research, both publicly, and most likely in private/government defense research. In a targeted situation, i.e. surveillance of a household of 6, this would work easily enough...but I doubt there is enough information to provide reliable (high AUC) tagging of ID in a public scenario oh hundreds to thousands of individuals.
> Researchers in Italy have developed a way to create a biometric identifier for people based on the way the human body interferes with Wi-Fi signal propagation.. can re-identify a person in other locations most of the time when a Wi-Fi signal can be measured. Observers could therefore track a person as they pass through signals sent by different Wi-Fi networks – even if they’re not carrying a phone.. their technique makes accurate matches on the public NTU-Fi dataset up to 95.5 percent.
if it's a public scenario, you don't need that, they're using wifi on people's persons to id them. The concern is more gait analysis, and by some accounts even lip reading is possible with mm-wave 5g.